The Curriculum Vitae is usually requested for academic positions including teaching, administration and research. A CV is also sometimes requested for international positions and graduate school applications. What you choose to include and emphasize on your own CV will depend on your audience. The search committee will often read your CV before your resume (in fact, many search committees request a CV and not a resume), so it should emphasize the experiences and accomplishments that have directed the course of your academic life to this search committee and that make you the best candidate for the position.